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Journal Articles

Determination of alkali and alkaline earth elements in radioactive waste generated from reprocessing plant by liquid electrode plasma optical emission spectrometry

Yamamoto, Masahiko; Do, V. K.; Taguchi, Shigeo; Kuno, Takehiko; Takamura, Yuzuru*

Journal of Radioanalytical and Nuclear Chemistry, 327(1), p.433 - 444, 2021/01

 Times Cited Count:0 Percentile:0.01(Chemistry, Analytical)

A simple, practical, and reliable analytical method for determination of Na, K, Ca, Sr, and Ba by liquid electrode plasma optical emission spectrometry is developed. Appropriate emission lines for quantification, interferences from co-existing elements, and effect of measurement conditions with cell damage have been investigated. The spike and recovery tests using actual sample have been performed for method validation, and negligible sample matrix effect has been observed. Consequently, the method is successfully applied to several radioactive wastes. The obtained data have been agreed well with data from computer calculation and inductively coupled plasma optical emission spectrometry within 10% difference.

Journal Articles

A New measuring method for elemental ratio and Vickers hardness of metal-oxide-boride materials based on Laser-Induced Breakdown Spectroscopy (LIBS)

Abe, Yuta; Otaka, Masahiko; Okazaki, Kodai*; Kawakami, Tomohiko*; Nakagiri, Toshio

Proceedings of 2019 International Congress on Advances in Nuclear Power Plants (ICAPP 2019) (Internet), 7 Pages, 2019/05

Since the hardness of fuel debris containing boride from B$$_{4}$$C pellet in control rod is estimated to be two times higher as that of oxide, such as UO$$_{2}$$ and ZrO$$_{2}$$, it is necessary to select the efficient and appropriate operation for removal of fuel debris formed in the severe accident of nuclear power plants. We focused on the characteristics of LIBS, an innovative rapid chemical in-situ analysis technology that enables simultaneous detection of B, O, and other metal elements in fuel debris. Simulated solidified melt specimens were obtained in the plasma heating tests (CMMR-0/-2, performed by JAEA) of simulated fuel assembly (ZrO$$_{2}$$ is used to simulated UO$$_{2}$$ pellet, other materials such as stainless steel, B$$_{4}$$C are same as fuel assembly). The LIBS signals of (B/O)/Zr ratio showed good linear relationship with Vickers hardness. This technique can be also applied as in-situ assessment tool for elemental composition and Vickers hardness of metal-oxide-boride materials.

Journal Articles

Spectroscopic study of reaction mechanism of laser-ablated silicon ions and neutrals with benzene molecules

Saeki, Morihisa; Oba, Hironori; Yokoyama, Atsushi

Journal of Physics; Conference Series, 59, p.732 - 735, 2007/00

 Times Cited Count:0 Percentile:0(Optics)

We have performed laser ablation of silicon in neon gas and benzene vapor. The reaction mechanism of the ablated silicon atoms with the neon atoms and benzene molecules were investigated by space- and time-resolved emission spectroscopy. The ablation in the neon gas suggested that (1) the neutral neon atoms are excited to 2pn states lying in 18-19 eV and (2) the neutral neon atoms are excited by electronic-to-electronic and translational-to-electronic energy transfer from the silicon ions. In the ablation in the benzene vapor, we found that the benzene molecules are decomposed into C2 and CH radicals by the collision with the silicon atoms.

Journal Articles

Curium(III) species and the coordination states in concentrated LiCl-aqueous solutions studied by time-resolved laser-induced fluorescence spectroscopy

Arisaka, Makoto; Kimura, Takaumi; Nagaishi, Ryuji; Yoshida, Zenko

Journal of Alloys and Compounds, 408-412, p.1307 - 1311, 2006/02

 Times Cited Count:6 Percentile:42.64(Chemistry, Physical)

no abstracts in English

Journal Articles

Electronic structure of carbon nitride thin films studied by X-ray spectroscopy techniques

Hellgren, N.*; Guo, J.*; Luo, Y.*; S${aa}$the, C.*; Agui, Akane; Kashtanov, S.*; Nordgren, J.*; ${AA}$gren, H.*; Sundgren, J.-E.*

Thin Solid Films, 471(1-2), p.19 - 34, 2005/01

 Times Cited Count:133 Percentile:96.54(Materials Science, Multidisciplinary)

no abstracts in English

Journal Articles

Speciation of Eu(III) in an anion exchange separation system with LiCl-H$$_{2}$$O/alcohol mixed media by time-resolved laser-induced fluorescence spectroscopy

Arisaka, Makoto*; Kimura, Takaumi; Suganuma, Hideo*; Yoshida, Zenko

Journal of Radioanalytical and Nuclear Chemistry, 255(2), p.385 - 389, 2003/02

 Times Cited Count:5 Percentile:36.77(Chemistry, Analytical)

no abstracts in English

Journal Articles

Uranium(VI) speciation at elevated temperatures and pressures by time-resolved laser-induced fluorescence spectroscopy

Kimura, Takaumi; Nagaishi, Ryuji; Ozaki, Takuo; Arisaka, Makoto*; Yoshida, Zenko

Journal of Nuclear Science and Technology, 39(Suppl.3), p.233 - 239, 2002/11

no abstracts in English

Journal Articles

Direct evidence for enchanced inner-sphere chloro complexation of Eu(III) and Cm(III) in anion exchange resin phase studies by time-resolved laser-induced fluorescence spectroscopy

Arisaka, Makoto*; Kimura, Takaumi; Suganuma, Hideo*; Yoshida, Zenko

Radiochimica Acta, 90(4), p.193 - 197, 2002/05

 Times Cited Count:14 Percentile:65.5(Chemistry, Inorganic & Nuclear)

no abstracts in English

Journal Articles

Sorption behavior and coordination state of Eu(III) and Cm(III) in hydrochloric acid-methanol mixture/cation exchange resin system studied by time-resolved laser-induced fluorescence spectroscopy

Arisaka, Makoto*; Kimura, Takaumi; Suganuma, Hideo*; Yoshida, Zenko

Radiochimica Acta, 89(8), p.593 - 598, 2001/08

 Times Cited Count:11 Percentile:61.93(Chemistry, Inorganic & Nuclear)

no abstracts in English

Journal Articles

Performance of soft X-ray emission spectrometer employing charge-coupled device detector

Sasaki, Teikichi; Chugan, Nobuhiko*; Muramatsu, Yasuji*

Nuclear Instruments and Methods in Physics Research A, 467-468(Part.2), p.1489 - 1492, 2001/07

 Times Cited Count:3 Percentile:28.26(Instruments & Instrumentation)

no abstracts in English

Journal Articles

Soft X-ray emission and absorption spectra in the C K region of sputtered amorphous carbon films

Muramatsu, Yasuji; Hirono, Shigeru*; Umemura, Shigeru*; Ueno, Yuko*; Hayashi, Takayoshi*; Grush, M. M.*; Gullikson, E. M.*; Perera, R. C. C.*

Carbon, 39(9), p.1403 - 1407, 2001/06

 Times Cited Count:18 Percentile:58.27(Chemistry, Physical)

no abstracts in English

Journal Articles

Soft X-ray emission and absorption spectra in the O K region of oxygen incorporated in microporous carbon

Muramatsu, Yasuji; Ueno, Yuko*; Ishiwata, Yoichi*; Eguchi, Ritsuko*; Watanabe, Masamitsu*; Shin, S.*; Perera, R. C. C.*

Carbon, 39(9), p.1359 - 1402, 2001/06

no abstracts in English

Journal Articles

Chemical bonding state analysis of silicon carbide layers in Mo/SiC/Si multilayer mirrors by soft X-ray emission and absorption spectroscopy

Muramatsu, Yasuji; Takenaka, Hisataka*; Ueno, Yuko*; Gullikson, E. M.*; Perera, R. C. C.*

Applied Physics Letters, 77(17), p.2653 - 2655, 2000/10

 Times Cited Count:13 Percentile:51.45(Physics, Applied)

no abstracts in English

JAEA Reports

None

; Aose, Shinichi; ; ;

PNC TN8420 93-014, 25 Pages, 1993/08

PNC-TN8420-93-014.pdf:3.02MB

None

JAEA Reports

None

; ; Aose, Shinichi; ; ;

PNC TN8410 93-165, 98 Pages, 1993/07

PNC-TN8410-93-165.pdf:3.26MB

None

JAEA Reports

None

; ; Aose, Shinichi; ; ;

PNC TN8410 93-081, 89 Pages, 1993/04

PNC-TN8410-93-081.pdf:4.42MB

None

JAEA Reports

Design construction and performance tests of atomic emission spectrograph with DCA and ICP excitation systems for plutonium bearing fuels

; Handa, Nuneo; Shiozawa, Kenichi; Hirata, Masaru; *

JAERI-M 90-062, 49 Pages, 1990/03

JAERI-M-90-062.pdf:2.4MB

no abstracts in English

Journal Articles

Isotopic analysis of lithium by hollow cathode excitation

Bunko Kenkyu, 39(2), p.102 - 109, 1990/00

no abstracts in English

63 (Records 1-20 displayed on this page)